I found exactly the anekdote in Surely You're Joking, Mr. Feynman, you can find a PDF online (which is apparently completely cool in the age of AI).
Notable parts of the story: it happened at Oak Ridge, and Emil Segrè was the one who originally went there for another reason (not Feynman as I misremembered) and he noticed all the scary shit they were doing with tanks of solution. They had no criticality safety whatsoever because the Army figured there was never to be more than a critical mass on the plant at one time. They had hazards with solutions, but also hazards with dry powders in boxes, presumably wood etc would act as a moderator. They resolved this by adding cadmium to things.
You can find the right chapter by searching for "Emil".
edit: and it was indeed uranyl nitrate (uranium nitrate in old terminology).
edit: and other thing to note about all that business is how a lot of it, like uranyl nitrate, was also extremely toxic.
As I understand in the short term and acutely, for uranium it was genuine chemical toxicity. Unlike for say radium for which even the longest living isotope is nowhere near as chemically toxic as its radioactivity. (Although I am not 100% sure for uranium 235 which is shorter living and all that)
The question of chemical vs radiation toxicity is one of those things that sound like "hmm, pilosophical", but (in most cases) is easily resolved by comparing different isotopes. I spend way too much time gazing into the abyss of radiation biocrackpots, and they often do a "prove me wrong" thing about chemical toxicity of radium, expecting it to go as if the question is unknowable, and not as if it had been settled in the most straightforward way forever ago.
Notable parts of the story: it happened at Oak Ridge, and Emil Segrè was the one who originally went there for another reason (not Feynman as I misremembered) and he noticed all the scary shit they were doing with tanks of solution. They had no criticality safety whatsoever because the Army figured there was never to be more than a critical mass on the plant at one time. They had hazards with solutions, but also hazards with dry powders in boxes, presumably wood etc would act as a moderator. They resolved this by adding cadmium to things.
You can find the right chapter by searching for "Emil".
edit: and it was indeed uranyl nitrate (uranium nitrate in old terminology).
edit: and other thing to note about all that business is how a lot of it, like uranyl nitrate, was also extremely toxic.
As I understand in the short term and acutely, for uranium it was genuine chemical toxicity. Unlike for say radium for which even the longest living isotope is nowhere near as chemically toxic as its radioactivity. (Although I am not 100% sure for uranium 235 which is shorter living and all that)
The question of chemical vs radiation toxicity is one of those things that sound like "hmm, pilosophical", but (in most cases) is easily resolved by comparing different isotopes. I spend way too much time gazing into the abyss of radiation biocrackpots, and they often do a "prove me wrong" thing about chemical toxicity of radium, expecting it to go as if the question is unknowable, and not as if it had been settled in the most straightforward way forever ago.
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